• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    There is provided a method for producing an optical fiber (10) comprising a glass fiber (13), a primary resin coating layer (14) which covers the periphery of the glass fiber (13), and a layer secondary resin coating coating (15) which covers the periphery of the primary resin coating layer (14), wherein the primary resin coating layer (14) is formed by curing a curable resin composition which comprises a or one or more oligomers, one or more monomers, and a reaction initiator, the curable resin composition containing a terminally capped oligomer in an amount of 30% by weight or greater based on all of the oligomers. The optical fiber (10) produced by this production method does not exhibit a deteriorated low temperature transmission loss since the primary resin coating layer (14) is inhibited from producing voids even when it has a low Young's modulus. .
    公开号:FR3024873A1
    申请号:FR1557704
    申请日:2015-08-13
    公开日:2016-02-19
    发明作者:Kazuyuki Sohma；Noriaki Iwaguchi；Takashi Fujii
    申请人:Sumitomo Electric Industries Ltd；
    IPC主号:
    专利说明:

    [0001] BACKGROUND TECHNICAL FIELD [0001] The present invention relates to an optical fiber and a method of producing the optical fiber. BACKGROUND ART Japanese Patent No. 4341872 discloses a radiation-curable liquid resin composition for the inner primary coating of optical fibers, the oligomer-containing composition having a reactive group at each of the two termini. It is necessary that the optical fibers have a resistance to lateral pressure. The lateral pressure resistance represents a non-sensitivity to the microbending induced transmission loss that occurs when lateral pressure is applied to the optical fiber. In order for an optical fiber to have lateral pressure resistance, the inner coating layer must have a reduced Young's modulus. According to the technique. As described in the patent document, it is necessary that the molecular weight of the oligomer be increased to reduce the Young's modulus of the primary coating of the optical fiber. In this case, however, the toughness of the primary coating has been reduced to cause a problem that polymer chains in the resin are subjected to irreversible fractures due to tension and accumulation thereof results in void production. . The presence of voids promotes the loss of transmission at low temperatures.
    [0002] SUMMARY OF THE INVENTION [0004] It is an object of the invention to provide an optical fiber in which the primary coating is inhibited from producing voids even when it has a low Young's modulus and thus does not deteriorate 3024873 2 the transmission loss at low temperature, and provide a method of producing the optical fiber. The invention provides, according to one aspect thereof, an optical fiber comprising a fiberglass which comprises a core and a sheath, a primary resin coating layer which covers the periphery of the glass fiber, and a secondary resin coating layer which overlies the periphery of the primary resin coating layer, wherein the primary resin coating layer is a layer formed by curing a curable resin composition which comprises one or more oligomers , one or more monomers, and a reaction initiator, the curable resin composition containing an oligomer terminated at a termination in an amount of 30% by weight or greater based on all of the oligomers.
    [0003] The invention provides, in another aspect thereof, a method of producing an optical fiber comprising a fiberglass which comprises a core and a sheath, a primary resin coating layer which covers the periphery of the fiberglass, and a secondary resin coating layer which overlies the periphery of the primary resin coating layer, wherein the primary resin coating layer is formed by curing a curable resin composition which comprises one or more a plurality of oligomers, one or more monomers, and a reaction initiator, the curable resin composition containing a terminally capped oligomer in an amount of 30% by weight or greater based on all of the oligomers. [0006] It is possible according to the invention to provide an optical fiber in which the primary coating is inhibited from producing voids even when it has a reduced Young's modulus and because, due to inhibited void production, excellent resistance to lateral pressure and does not deteriorate the transmission loss at low temperatures.
    [0004] BRIEF DESCRIPTION OF THE DRAWINGS [0007] FIG. 1 is a schematic cross sectional view illustrating an embodiment of the optical fiber of the invention.
    [0005] Fig.
    [0006] 2A is a schematic cross-sectional view illustrating the state in which oligomer chains derived from a terminated capped oligomer are intertwined in the primary resin coating layer of an embodiment of the optical fiber of the invention. invention. Fig.
    [0007] 2B is a schematic cross-sectional view illustrating the state in which oligomer chains derived from a terminated capped oligomer are intertwined in the primary resin coating layer of an embodiment of the optical fiber of the invention. 'invention. DETAILED DESCRIPTION [0008] [Explanation of Embodiments of the Invention] Embodiments of the optical fiber according to the invention have any of the following aspects (1) to (8). (1) An optical fiber comprising a glass fiber which comprises a core and a sheath, a primary resin coating layer which covers the periphery of the glass fiber, and a secondary resin coating layer which covers the periphery of the fiberglass; the primary resin coating layer, wherein the primary resin coating layer is a layer formed by curing a curable resin composition which comprises one or more oligomers, one or more monomers, and a reaction initiator, the curable resin composition containing an oligomer terminated at a termination in an amount of 30 ° A) by mass or higher based on all the oligomers. The optical fiber having the appearance (1) shown above is expected to produce the following effects since the curable resin composition to form the primary resin coating layer contains an end-capped oligomer in an amount of 30% by weight or greater based on all oligomers.
    [0008] The oligomer in the primary resin coating layer has a reduced cross-linking site density so that the primary resin coating layer may have a low Young's modulus. In addition, as shown in FIG.
    [0009] 2A, the side portions of non-reactive (capped) oligomer chain terminations (continuous-line portions) derived from the terminated capped oligomer are intertwined with oligomer chains derived from another oligomer, or Oligomer chains are electrically bonded to each other. This "entanglement" or "electrical connection" constitutes a pseudo-crosslinking. This pseudo crosslinking is different from the actual crosslinking, such as that shown in FIG.
    [0010] 2B, formed by bonding between the reactive groups of a difunctional oligomer which has reactive groups at both termini (the oligomer chains are dotted line portions), and the molecular chains extend, without breaking, by application. voltage to these and return to the original state when the voltage is removed. As a result, the primary resin coating layer is inhibited from producing voids therein and deterioration of the low temperature transmission loss is avoided. (2) It is preferable that the optical fiber is an optical fiber comprising a fiberglass which comprises a core and a sheath, a primary resin coating layer which covers the periphery of the fiberglass, and a secondary resin coating layer which covers the periphery of the primary resin coating layer, wherein the primary resin coating layer is a layer formed by curing a curable resin composition which comprises one or more oligomers, a or a plurality of monomers, and a reaction initiator, the curable resin composition containing a terminally capped oligomer in an amount of 60% by weight or greater based on all of the oligomers. This is because the effect described above is promoted in this optical fiber. (3) It is even more preferred that the curable resin composition contain the terminated capped oligomer in an amount of 80% by weight or greater based on all of the oligomers. This is because the effect is further promoted. (4) It is preferred that the reactive termination of the terminated capped oligomer is a hydroxyalkyl acrylate residue. This is because high photoreactivity can be imparted. (5) It is preferred that the oligomers contained in the curable resin composition comprise a urethane (meth) acrylate oligomer. This is because this composition is suitable for obtaining a cured object having high strength and high elongation. (6) It is preferred that the glass fiber have an effective web cross section of 115 μm 2 or greater and that the primary resin coating layer has a Young's modulus of 0.5 MPa or less. This is because not only can the high lateral pressure resistance of the optical fiber be ensured but the deterioration of the low temperature transmission loss is also remarkably mitigated. (7) It is preferable that the primary resin coating layer has a Young's modulus of 0.3 MPa or less. This is because not only can the high lateral pressure resistance of the glass fiber be ensured but the deterioration of the low temperature transmission loss is also remarkably mitigated. The embodiments of the method according to the invention for producing an optical fiber have the following aspect (8). (8) A method of producing an optical fiber comprising a fiberglass which comprises a core and a sheath, a primary resin coating layer which covers the periphery of the glass fiber, and a resin coating layer secondary coating which covers the periphery of the primary resin coating layer, wherein the primary resin coating layer is formed by curing a curable resin composition which comprises one or more oligomers, one or more monomers, and an initiator In one embodiment, the curable resin composition containing a terminally capped oligomer in an amount of 30% by weight or greater based on all of the oligomers. Embodiments of the invention are explained below in detail with reference to FIG. 1. 5 (Sketch of the optical fiber) Fig. 1 is a schematic cross sectional view illustrating an embodiment of the optical fiber of the invention. The optical fiber 10 comprises a glass fiber 13 and, disposed on its periphery, a resin coating layer 16 which comprises an inner layer 14 and an outer layer 15 which have each been formed from a curable resin composition ultraviolet light (hereinafter also referred to simply as "resin composition"). The fiberglass 13 consists of a core 11 and a sheath 12. From the quartz to which germanium has been added may be used, for example, for the core 11, and either pure quartz or quartz to which fluorine may be used for sheath 12. In FIG. 1, the diameter (D2) of the glass fiber 13 is for example about 125 pm. The resin coating layer 16 is comprised of two layers, i.e., an inner layer 14 and an outer layer 15. The overall thickness of the resin coating layer 16 is usually 62.5 μm. . The thickness of the inner layer 14 and that of the outer layer 15 are substantially identical, and are each 20-40 μm. The thickness of the inner layer 14 may be specifically 37.5 μm, and that of the outer layer 15 may be 25 μm. [0014] (Resin Compositions) In this embodiment, the resin compositions for forming the resin coating layer each comprise one or more oligomers, one or more monomers, and a reaction initiator. Oligomers 3024 873 7 Examples of the oligomers include urethane acrylates, epoxy acrylates or mixtures thereof. Urethane acrylates are preferred. Examples of the urethane acrylates include those obtained by reacting a polyol compound, a polyisocyanate compound, and a hydroxyl group-containing acrylate compound. Examples of the polyol compound include poly (tetramethylene glycol), poly (propylene glycol), and a diol of bisphenol A / ethylene oxide adduct. Examples of the polyisocyanate compound include 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, and isophorone diisocyanate. Examples of the hydroxyl group-containing acrylate compound include 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxybutyl acrylate, 1,6-hexanediol monoacrylate, pentaerythritol triacrylate, and the like. 2-hydroxypropyl acrylate, and tripropylene glycol diacrylate. [0016] The resin composition for forming the inner layer 14 contains a terminally capped oligomer in an amount of 30% by weight or greater based on all of the oligomers. In this description of the invention, a non-reactive termination of an oligomer is called a "capped termination". One endcapped oligomer indicates an oligomer that has a non-reactive termination and a reactive group at the other end. Non-reactive termination can be achieved by deactivating a reactive group in the termination. The content of this terminally capped oligomer is preferably 40% by weight or greater, more preferably 80% by weight or greater. It is preferred that the reactive termination of this terminally capped oligomer be a hydroxyethyl acrylate residue. Either a lower alcohol having up to 5 carbon atoms or a silane coupling agent has been linked to the other end. As the silane coupling agent, there may be used different silane coupling agents having a reactive functional group which is amino, epoxy, (meth) acryloyl, vinyl, or mercapto. [0017] 3024873 8 (Monomers) Examples of the monomers include N-vinyl monomers having a ring structure, such as for example Nvinylpyrrolidone, N-vinylcaprolactam, and acryloylmorpholine. These monomers are preferred since the resin composition containing any of these monomers has an improved cure rate. In addition to these, monofunctional monomers, such as isobornyl acrylate, tricyclodecanyl acrylate, benzyl acrylate, dicyclopentanyl acrylate, 2-hydroxyethyl acrylate, Nonylphenyl, phenoxyethyl acrylate, and poly (propylene glycol) monoacrylate and polyfunctional monomers, such as poly (ethylene glycol) diacrylate, tricyclodecanediyldimethylene diacrylate, or diacrylate diols of bisphenol Ajethylene, are usable. [Reaction Initiator] Examples of the reaction initiator include 1-hydroxycyclohexylmethylketone, 2,2-dimethoxy-2-phenylacetophenone, 1- (4-isopropylphenyl) -2-hydroxy-2-methylpropan 1-one, 2,4,4-trimethylpentylphosphine oxide, 2,4,4-trimethylbenzoyl-diphenylphosphine oxide, 2-methyl-1,4- (methylthio) phenyl] -2-morpholinopropan-1 -one (Irgacure 907, manufactured by Ciba Specialty Chemicals Co.), and 2,4,6-trimethylbenzoyldiphenylphosphine oxide (Lucirin TPO, manufactured by BASF AG). [Other ingredients] The resin compositions may contain a silane coupling agent, an antioxidant, a photosensitizer, and the like. [0020] (Other properties) The fiberglass 13 has in this embodiment an effective cross-sectional area of the core of 115 pm 2 or greater, and the inner layer 14 has a Young's modulus of 0.5 MPa or less . It is preferred, however, that the effective cross section of the core be 130 pm 2 or greater and that the Young's modulus be 0.3 MPa or less.
    [0011] The Young's modulus of the inner layer 14 (primary coating layer) is measured by the following method. Internal layer 14: Young's modulus is measured by a pull module test at 23 ° C. The resin coating layer 16 of the optical fiber 10 is specifically incised with a razor blade or the like to cut the resin coating layer 16, and the optical fiberglass 13 is pulled while maintaining the coating layer of resin 16 (inner layer 14 and outer layer 15) attached. The stress imposed on the inner layer 14 is determined from the amount in which the inner layer 14 is subjected to elastic deformation before the optical fiberglass 13 is pulled and from the force used to pull the fiber from the fiber. In the meantime, it is necessary for the optical fiber to have a high optical signal-to-noise ratio (OSNR) so that an optical fiber has higher per-core communication capability by digital communication technology. coherent comprising a multi-level modulation technology. One method of improving OSNR is to reduce nonlinearity.
    [0012] It is necessary to reduce the non-linearity of increasing the effective cross sectional area of the fiberglass core as much as possible and to reduce the transmission loss. However, the first solution, i.e., increasing the effective cross-section of the core, indicates that the optical fiber tends to have poor lateral pressure resistance and it becomes necessary that the Primary resin has a Young's modulus as low as 0.20 MPa or less. In the case of forming a primary resin coating layer having a low Young's modulus, a conventional method for this is to increase the molecular weight of the oligomer to be incorporated into a resin composition to form the primary resin coating layer, thereby forming a sparse polymer network (lowering the density of the crosslinking sites). The resin coating layer formed by this method, although having improved elongation, however, exhibits reduced strength and has the problem that polymer chains in the resin are subjected to irreversible voltage cuts. and an accumulation thereof results in void production in the resin coating layer during handling. In the case where there is no vacuum, the transmission loss at 5 -40 ° C is less than the transmission loss measured at 23 ° C. In the case where there are voids, the transmission loss at -40 ° C is however greater than the transmission loss measured at 23 ° C; the presence of voids promotes the loss of transmission at low temperatures. In this embodiment, a resin composition containing a terminally capped oligomer in an amount of 30% by weight or greater based on all of the oligomers was used to form the inner layer 14 so that avoiding that the optical fiber suffers from producing voids in the primary resin coating layer even when this coating layer has a low Young's modulus and thereby avoid deterioration of the low temperature transmission loss. As a result, the inner layer 14 can be made to have a low Young's modulus, and this layer extends, without breaking, upon application of a voltage thereto and returns to the state of origin when removing the voltage. It is thus possible to obtain an optical fiber for which the deterioration of the transmission loss at low temperature is avoided. [Examples] [0023] The results of the evaluation tests to which the examples according to the present invention and the comparative examples were submitted are shown below to explain the invention in more detail. The invention is not limited to the following examples. [Production of Optical Fibers 10] Glass fibers 13 were each made of a core and a sheath and had an outer diameter (D2) of 125 .mu.m. effective cross section of the core being shown in Table 1 given below. The resin composition for the inner layer formation and the resin composition for outer layer formation which respectively had the constitutions shown below were applied to the peripheral surface of each glass fiber 13 and were hardened. to cover the surface with two layers (an inner layer 14 and an outer layer 15), thereby forming a resin coating layer 16. Optical fibers 10 have thus been produced. The thickness of the inner layer 14 was regulated at 35 μm, and the thickness of the outer layer 15 was regulated at 25 μm. [0025] (Resin composition for the formation of inner layer) Urethane acrylate oligomer (s) having the constitution shown in Table 1 65 parts by weight Ethoxynonylphenyl acrylate 5.5 parts by weight Acrylate isobornyl 20.5 parts by weight N-vinylcaprolactam 7.0 parts by weight 2,4,4-trimethylbenzoyldiphenylphosphine oxide (reaction initiator) 1.2 parts by weight (Additives) Antioxidant, Irganox 1035 0.8 parts by weight Light Stabilizer, 2-hydroxy-4-methoxybenzophenone 0.15 parts by weight [Resin composition for external layer formation] Urethane acrylate oligomer obtained by reaction of diisocyanate and hydroxy acrylate with poly (propylene glycol) diol 50 parts by mass Epoxy acrylate 20 parts by mass Isobornyl acrylate 10 parts by weight N-vinylpyrrolidone 5 parts by weight Ethoyenylphenyl acrylate 15 parts by weight 30 Oxide of 2,4 , 4-triméthylbenzoyldiphénylph osphine (reaction initiator) 2 parts by weight [Evaluation of the optical fibers 10] Each of the optical fibers produced was subjected to the following evaluation tests (Young's modulus of the inner layer, loss of 3024873 12 low temperature). The results of these are shown in Table 1 below. [0028] (Young's modulus of the inner layer) The Young's modulus of the inner layer 14 was measured by a pull module test at 23 ° C. The resin coating layer 16 of the optical fiber 10 has been specifically incised with a razor blade or the like to cut the resin coating layer 16, and optical fiberglass 13 has been drawn while maintaining the layer of 10. resin coating 16 (inner layer 14 and outer layer 15) attached. The stress imposed on the inner layer 14 was determined from the amount in which the inner layer 14 was subjected to elastic deformation before the optical fiberglass 13 was pulled and from the force used to pull the The results of this are shown in Table 1 below. [0029] (Lateral pressure resistance) The difference in transmission loss was determined by subtracting the transmission loss of the optical fiber in the loose and looped state of bundling, without winding around a coil, the transmission loss of the same optical fiber in the state wound around a coil on the body of which a metal grid has been wound. The grid consists of a metal cable having an outer diameter of 50 μm. The grid pitch was 150 μm. The case in which this difference was less than 0.6 dB / km is indicated by A, the case in which this difference was greater than or equal to 0.6 but less than 1.0 is indicated by B, and the case in which difference was greater than or equal to 0.1 is indicated by C; A and B have been estimated as acceptable. [Low Temperature Transmission Loss] A voltage of 2.2 kg was applied to the optical fiber 10 using a vertical axis winch device and a winder. For the optical fiber to which the voltage has been applied, the signal transmission property having a wavelength of 1550 nm has been investigated under the respective temperature conditions of 30.degree. 40 ° C. The transmission loss at 23 ° C and -40 ° C was thus evaluated for the optical fiber 10. The case in which the difference between the transmission loss at -40 ° C and the transmission loss at 23 ° C (difference in transmission loss) was less than 0 dB / km was evaluated by A, the case in which this difference was greater than or equal to 0 dB / km but less than 0.01 dB / km was evaluated by B, and the case in which this difference was greater than or equal to 0.01 dB / km was evaluated by C. The values evaluated by A and B were acceptable. The results of these are shown in Table 1 below. [0031] Numbers 1 to 18 are examples and Nos. 19 to 30 are comparative examples in the following Table 1. Table 1 No. Composition of urethane acrylate oligomer Cross section Young's module Transmission loss Resistance to and average molecular weight of it in effective core from inner layer to low temperature pressure resin composition for the formation of inner layer fiberglass (pm2) (MPa) * 1 1 A 80 5_0.1 AA 2 A 115 .50.1 AA 3 A 130 50.1 BA 4 A 150 5_O, 1 BA 5 A 165 _50.1 BA 6 B 115 .50.2 AA 7 B 130 .50.2 AA 8 B 150 5_0.2 AA 9 B 165 .50.2 AA 10 C 115 50.3 AA 11 C 130 5_0.3 AB 12 C 150 .50.3 AB 13 C 165 5.03 AB 14 D 80 50.5 AA 15 D 115 .50.5 AA 16 D 130 5O, 5 AA Table 1 (cont.) Constitution No. urethane acrylate oligomer cross section Young's modulus Transmission loss Resistance to and average molecular weight of it in effective core of low temperature inner layer pressure resin composition for fiber formation glass (pm2) ( MPa) internal layer side * 1 17 D 150 50.5 AB 18 D 165 5_O, 5 AB 19 E 115 5.O, 7 AC 20 E 130 5_ 0, 7 AC 21 E 150 5. 0, 7 AC 22 E 165 5_0.7 AC 23 F 115 5.0.9 AC 24 F 130 50.9 AC 25 F 150 50.9 AC 26 F 165 5.0.9 AC 27 G 115 50.3 AC 28 G 130 5.
    [0013] 0 3 CB 29 G 150 5_0.3 CB 30 G 165 _50.3 CC 3 0 2 4 8 7 3 16 [0033] * 1 Constitution of urethane acrylate oligomer (all ° h are by mass) A 100% terminated oligomer 0% end-reactive oligomer Average molecular weight 4,500 B: 80 ° terminated oligomer A) 2-end reactive oligomer 20% Average molecular weight 4,500 10 C: Capped oligomer 60% termination Oligomer reactive at both termini 40% Average molecular weight 4,500 D: Terminated oligomer 30 ° h Reactive oligomer at both termini 70 ° h 15 Average molecular weight 4,500 E: Terminated oligomer 20% Oligomer reagent at both termini 80 ° h Average molecular weight 4,500 F: Oligomer capped at 0% termination Oligomer reactive at both termini 100 ° h Average molecular weight 4,500 G: Oligomer capped at 0% termination Oligomer reactive at Terminals 100% Average Molecular Weight 6,500 [0034] The structures of the terminated capped oligomer and the reactive oligomer at both termini are as follows. End-capped Oligomer: H- (I-poly (propylene glycol)) 2-I-MeOH 30 Reactive oligomer at both termini: H- (I-poly (propylene glycol)) 2-IH [0035] In the terms of oligomers, H represents a hydroxyethyl acrylate residue, I represents an isophorone diisocyanate residue, MeOH represents a methanol residue, and poly (propylene glycol) represents a poly (propylene glycol) residue. Optical fibers Nos. 1 to 13 shown in Table 1 were each capable of exhibiting low transmission loss at a reduced temperature relative to a value in the acceptable range and further exhibited a difference in temperature. loss of transmission with respect to the lateral pressure resistance which has been reduced to a value within the acceptable range since the resin compositions for inner layer formation contained an end-capped oligomer in an amount of 60% by mass or greater on the basis of all the oligomers. It can be seen from a comparison between Nos. 10 to 13 and Nos. 27 to 30 that the configuration of the invention made it possible to achieve a reduction in the transmission loss at low temperature, although the first and last configurations presented the same Young model.
    [0014] Optical fibers Nos. 14 to 18 were each capable of exhibiting a reduced low temperature transmission loss at a value in the acceptable range and further exhibited a difference in transmission loss with respect to reduced lateral pressure resistance. to a value within the acceptable range since the resin composition contained a terminally capped oligomer in an amount of 30% by weight or greater based on all of the oligomers. Optical fibers Nos. 1 to 9 shown in Table 1 were each capable of particularly exhibiting a reduced low temperature transmission loss and in the measured value for lateral pressure resistance (rated by A) regardless of the cross-sectional area. the core fiber resins compositions contained an end-capped oligomer in an amount of 80% by weight or greater based on the totality of the oligomer (s) .
    权利要求:
    Claims (8)
    [0001]
    REVENDICATIONS1. An optical fiber comprising a fiberglass which comprises a core and a sheath, a primary resin coating layer which overlies the periphery of the glass fiber, and a secondary resin coating layer which overlies the periphery of the cladding layer of the primary resin, wherein the primary resin coating layer is a layer formed by curing a curable resin composition which comprises one or more oligomers, one or more monomers, and a reaction initiator, the resin composition curable agent containing a terminated capped oligomer in an amount of 30% by weight or greater based on all of the oligomers.
    [0002]
    The optical fiber of claim 1, wherein the curable resin composition contains a terminally capped oligomer in an amount of 60% by weight or greater based on all of the oligomers.
    [0003]
    The optical fiber of claim 2, wherein the curable resin composition contains the terminated capped oligomer in an amount of 80% by mass or greater based on all of the oligomers.
    [0004]
    An optical fiber according to any one of claims 1 to 3, wherein the reactive termination of the terminated capped oligomer is a hydroxyethyl acrylate residue. 25
    [0005]
    An optical fiber according to any one of claims 1 to 4, wherein the oligomers contained in the curable resin composition comprise a urethane (meth) acrylate oligomer.
    [0006]
    An optical fiber according to any one of claims 1 to 5, wherein the optical fiber has an effective core cross section of 115 μm 2 or greater and the primary resin coating layer has a Young's modulus of 0. , 5 MPa or less.
    [0007]
    An optical fiber according to any one of claims 1 to 6, wherein the primary resin coating layer has a Young's modulus of 0.3 MPa or less. 35
    [0008]
    A process for producing an optical fiber comprising a fiberglass which comprises a core and a sheath, a primary resin coating layer which covers the periphery of the glass fiber, and a coating layer of secondary resin which covers the periphery of the primary resin coating layer, wherein the primary resin coating layer is formed by curing a curable resin composition which comprises one or more oligomers, one or more monomers, and a reaction initiator, the curable resin composition containing a terminally capped oligomer in an amount of 30% by mass or greater based on all of the oligomers.
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    JP2014164879|2014-08-13|
    JP2014164879A|JP6369215B2|2014-08-13|2014-08-13|Optical fiber core and manufacturing method thereof|
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